Glass Volumetric
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Glass Volumetric

Qualitative Versus Quantitative Analyses
The science of qualitative analysis is based on the fact that every element and compound has distinctive properties such as melting point, boiling point, color, texture, density, and so on. Every element reacts with several chemicals in very distinctive ways. For example, the lead used in house paints react with hydrogen sulfide to form a distinctive black precipitate. As known to us people are now concerned about the presence of lead in our environment due to lethality of its toxicity as Lead is a highly toxic element that can cause both mental and physical problems and, in high doses, even death. Suppose that a person wants to know if the paint used on his or her house contains lead. That person can take a sample of the paint to a chemist for qualitative analysis and the chemist can perform necessary analysis in order to let him know whether or not lead is present in the paint.
In many instances, the question facing a chemist is similar to the lead problem described above as very often we are required to know as to what element or elements are present in some unknown mixture. Chemists have developed a systematic method for answering these questions. The method divides the most common metallic chemical elements into about six groups. The elements are grouped in each case according to the way they react with some specific chemical. The three elements in Group I of the system, for example, are silver, lead, and mercury. These elements are grouped together because, when treated with hydrochloric acid, they all form a solid metallic chloride and precipitate out of solution. Similarly, the seven elements in Group II are grouped together because they all form precipitates with hydrogen sulfide in acidic medium. And so on. In fact Qualitative analysis is a process-of-elimination procedure. A chemist tests first for one group of elements (Group I in this case) and makes a note of any elements found in this group. He or she then tests for a second group of elements (Group II) and makes a note of any additional elements found in this group. Eventually, every element is either identified or eliminated from consideration.
A number of mechanical devices have been invented to identify elements and compounds on the basis of certain physical properties. The mass spectrometer is one such instrument. In a mass spectrometer, an unknown material is first vaporized (converted into a gas) and then accelerated into the middle of a large magnet. The material travels along a curved path within the magnet and emerges onto a photographic plate. The shape of the path taken by the particles that make up the material and the point of impact they make on the photographic plate are determined by the mass and the velocity of the particles. For example, helium atoms, hydrogen molecules, and chlorine molecules all travel through the magnet in distinctive pathways that can be recorded on the photographic plate. Chemists can study the photographic images made in a mass spectrograph and identify the particles that made those images.
Chromatography is another system for identifying the components of a mixture. In a chromatography column, a mixture of substances is allowed to pass through a long column containing some sticky material. Each component of the mixture has a different tendency to stick to the material. Chemists can look at the pattern of materials attached to the chromatography column and determine which substances were present in the original mixture. One area in which qualitative analysis has become very important is the matching of human DNA tissue by law enforcement agencies to prove the presence or absence of a person at a crime scene.
The term quantitative analysis is used to describe any procedure by which the concentration, generally percentage composition of any compound or mixture is determined. For example, we might be required to know the exact composition of some new compound that has been discovered. Or we might want to find out what the percentage of gold is in a new ore that has been discovered. Both of these questions can be answered by the procedures of quantitative analysis. Quantitative techniques in general are divided into two categories namely: wet or classical techniques and instrumental methods.
Classical methods have been used since the beginning of modern chemistry in the nineteenth century. They generally make use of balances and calibrated glass containers to measure the percentage composition of a compound or mixture. For example, the procedure known as gravimetric analysis involves the addition of some chemical to the unknown compound or mixture to produce a precipitate. A precipitate is a solid formed during a chemical reaction, usually in water, that eventually settles out of the solution. In a gravimetric analysis, the precipitate is filtered, washed, dried, and weighed. The composition of the original unknown material can then be calculated from the weights of the precipitate and sample and original unknown. Another classical form of quantitative analysis is known as volumetric analysis. Volumetric analysis uses a procedure known as titration, in which a solution, known as the standard solution, whose concentration is known precisely, is caused to react with an unknown sample. The amount of this known solution needed to react precisely with the sample of the unknown solution can be used to calculate the percentage composition of the unknown solution.
Suppose that someone shines a beam of X- rays at a sample of gold metal. Those X- rays will cause electrons in gold atoms to become excited and give off light. The same result can be produced with any one of the 100 or so chemical elements. The only difference is that the electrons of each element respond differently to the beam of X- rays. This means that a chemist can decide which element or elements are present in a substance by shining X- rays on the substance and observing the light pattern that is produced.
Forms of energy other than X- rays can be used to produce the same results. For example, different elements conduct an electric current more or less effectively. In some cases, the presence of various elements in an unknown sample can be discovered, then, simply by passing an electric current through the sample and measuring the electrical conductivity in the sample. Instrumental techniques have made possible a much greater sensitivity in the analysis of unknown materials. In most classical forms of analysis, an accuracy of about one part per thousand is not unusual (meaning one milligram of some substance is detectable in a one-gram sample). Instrumental techniques have the capability to detect concentrations of one part per million, one part per billion, and, in the very best cases, one part per trillion. At that level of sensitivity, it would be possible to detect a grain of sand in a volume of water equal to about three typical medium sized swimming pools.
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